By Dongfang Yang
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Extra info for Alkali-ion Batteries
98O4 nanoparticles retained a well-developed octahedral structure with sharp edges after surface treatment and exhibited particle sizes in the range of 20–50 nm. 98O4 (d) shows smoother particles. 98O4 appears infused with the PtAu nanoparticles having a bumpy morphology with only some aggregates . All the coated LiMn2O4 samples have increased surface area, which favors the penetration of electrolyte, decreasing the diffusion length of Li+ and electrons, and improves the overall activity of the cathode.
98O4 (b–d) at 16 kHz. 1. Electrochemical analysis The ability of the metal alloy to enhance LiMn2O4 redox properties has been confirmed. 1 mV s-1. The pristine LiMn2O4 shows several peaks, which are ascribed to the Mn3+/4+ redox reaction and constituents in the cathode material. Similar peak pairs are also found in the profiles of all functionalized samples with some shifts in potential and current. This demonstrates that coating does not change the electrochemical behavior but only the kinetics of LiMn2O4.
Hu, C. S. Wang. Electrospun Sb/C Fibers for a Stable and Fast Sodium-Ion Battery Anode. ACS Nano 7 (2013) 6378. Chapter 2 Capacity Optimization Nanotechnologies for Enhanced Energy Storage Systems Natasha Ross and Emmanuel I. 5772/62319 Abstract Rechargeable lithium-ion battery (LIB) cathodes consist of transition metal oxide material, which reversibly (de)intercalates lithium at a high potential difference versus a carbon anode. Manganese oxide cathode material offers lower cost and toxicity than the normally used cobalt.