Acidity and Basicity by Eike Brunner, Harry Pfeifer (auth.)

By Eike Brunner, Harry Pfeifer (auth.)

This is the 1st guide on zeolites and different microporous fabrics. it's an up to date, hugely refined number of details should you take care of zeolites in or at educational associations in addition to being a advisor for newcomers.

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31 P MAS NMR spectroscopic studies of trimethylphosphine adsorbed on zeolite H – Y and on γ -alumina were carried out by Lunsford et al. [108, 109], and of various trialkylphosphines adsorbed on silica-alumina and on γ -alumina by Maciel et al. [110]. Values for the resonance shifts relative to solid trimethylphosphine are given in Table 7. The sensitivity of trimethylphosphine to distinguish between different sorts of Lewis acid sites seems to be less than that of pyridine since only one type of Lewis acid site could be found for γ -alumina (see Table 7).

9 ZSM-5 Zeolites . . . . . . . . . . Influence of the Probe Molecule . . . . . Effect of Adsorption Temperature . . . . Difference in Preparation Procedures . . . Effect of Pretreatment . . . . . . . . Effect of Proton Exchange Level . . . . . Influence of the Si/Al Ratio and Dealumination Metal-Modified ZSM-5 .

116 116 116 116 117 118 119 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 Other Molecular Sieves . . . . . Aluminophosphates (VPI, AlPO4 ) . . Silicoaluminophosphates (SAPOs) . . Metal Aluminophosphates (MeAPOs) .

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